Cis-Bis(2,2′-Azopyridinido)dicarbonylruthenium(II)
نویسندگان
چکیده
An [Ru(apy)2Cl2] precursor (apy = 2,2′-azopyridine) in 2-methoxyethanol was heated under a pressurized CO atmosphere to afford diradical complex, [Ru(apy·−)2(CO)2], containing one-electron-reduced azo anion radical ligands. The electronic states of the complex were characterized by spectroscopic techniques and computational studies. Magnetic measurements revealed existence antiferromagnetic interactions complex.
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ژورنال
عنوان ژورنال: Molbank
سال: 2021
ISSN: ['1422-8599']
DOI: https://doi.org/10.3390/m1182